This new volume covers the latest developments in the field of electrochemistry. It addresses a variety of topics including new materials development, materials synthesis, processing, characterization, property measurements, structure-property relationships, and device performance. A broader view of various electrochemical energy conversion devices make this book a critical read for scientists and engineers working in related fields.
Papers from the symposium at the 102nd Annual Meeting of The American Ceramic Society, April 29-May 3, 2000, Missouri and the 103rd Annual Meeting, April 22-25, 2001, Indiana.
Preface ix
Papers from 2000 Annual Meeting
Oxygen Permeation Properties of the Intergrowth Oxide Sr3-x, La x Fe2-y, Co y O7-ä 3
F. Prado,T. Armstrong, A, Manthiram, and A. Caneiro
Structural Stability of Lithium-Extracted Li l-x, Ni l-y, Co y O2 II
R.V. Chebiam, F. Prado, and A. Manthiram
Reaction Kinetics and Mechanism of Formation of LiNi02 from Particulate Sol-Gel (PSG) Derived Precursors 19
C. C. Chang, J.Y Kim, Z. G.Yang, and R N. Kumta
Phase Evolution as a Function of Synthesis Temperature in the Li Mn3 0 4 t 8 (0.7 $ y =£ 1.33) System 27
S. Choi and A. Manthiram
Si/TiN Nanocomposite Anodes by High-Energy Mechanical Milling 35
l.-S. Kim, R N. Kumta, and G. E. Blomgren
Papers from 2001 Annual Meeting Gas Separation Membranes
Oxygen Permeation Through Mixed Conducting Perovskite Oxide Membranes 49
H. J. M. Bouwmeester and L M. van der Haar
Oxygen Permeation Properties of Perovskite-Related Intergrowth Oxides in the Sr-Fe-Co-O System 59
F. Prado,T. Armstrong, and A. Manthiram
Fe-Doped LaGa03-Based Perovskite Oxide as an Oxygen-Separating Membrane for CH4 Partial Oxidation 69
T. Ishihara.YTsuruta, H. Nishiguchi, and Y Takita
Synthesis and Oxygen Permeation Properties of Sr2.7, Lan0.3 ,Fe2-y, My, 07-8 7 S (M = Mn, Co and Ni) 79
F. Prado and A. Manthiram
Fuel Cells
Low-Cost Manufacturing Processes for Solid Oxide Fuel Cells 91
M. M. Seabaugh, B. E, McCormick, K. Hasinska, C.T. Holt, S. L Swartz, and W. J. Dawson
Manufacturing Routes and State of the A r t of the Planar Julich Anode-Supported Concept for Solid
Oxide Fuel Cells 99
W. A. Muelenberg, N. H. Menzler, H. R Buchkremer, and D. Stover
Materials and Microstructures for Improved Solid Oxide Fuel Cells 109
S. Huss, R. DoshiJ. Guan, G. Lear, K. Montgomery, N. Minh, and E. Ong
Pulsed Laser Deposition and DC-Sputtering of Yttria- Stabilized Zirconia for Solid Oxide Fuel Cell Applications 117
B. Hobein.W. A. Muelenberg, F.Tietz, D. Stover, E. W. Kreutz, M. Cekada, and R Panjan
Microstructure-Electrical Property Relationship in Nanocrystalline Ce02Thin Films 127
V. Petrovsky, B. R Gorman, H. U. Anderson, and T Petrovsky
Electrical Measurements in Doped Zirconia- Ceria Ceramics 137
C. R. Foschini, L Perazolli. J. A. Várela, D. R F. Souza, and R I. R Filho
Effects of Dissolution and Exsolution of Ni inYSZ 147
S. Linderoth and N. Bonanos
Multilayered Ceramic Reactor for the Steam Reforming of Methanol into Hydrogen-Enriched Gas 157
D. Gervasio, S. Rogers, R. Koripella, S.Tasic, D. Zindel, R. Changrani, C. K. Dyer J. Hallmark, and D.Wilcox
Si02-P205-Zr02 Sol-Gel/Nafion Composite Membranes for PEMFC 167
M. Aparicio, L C. Klein, K.I Adjemian, and A, B. Bocarsly
Study of Glass/Metal Interfaces Under an Electric Field: Low Temperature/High Voltage 177
M.A.Alvarez and L C. Klein
Lithium-Ion Batteries
Olivine-Type Cathodes for Lithium Batteries 189
A.Yamada, M. Hosoya, S. C. Chung, and K. Hinokuma
Amorphous Manganese Oxide Cathodes for Rechargeable Lithium Batteries 205
D. Im and A. Manthiram
Synthesis and Electrochemical Properties of Spinel LiCo204 Cathodes 215
S. Choi and A. Manthiram
Designing Structurally Stable Layered Oxide Cathodes for Lithium-Ion Batteries 225
S. Choi and A. Manthiram
Modeling and Design of Intermetallic Electrodes for Lithium Batteries 235
R. Benedek, J.T.Vaughey, and M. M.Thackeray
New Nanostructured Silicon and Titanium Nitride Composite Anodes for Li-Ion Batteries 249
l.-S. Kim, R N. Kumta, and G. E. Blomgren
Index 259
