Inhaltsangabe1 Introduction.- References.- 2 Corrosion Reactions and Corrosion Products.- References.- 3 Chemical Thermodynamics of Corrosion.- 3.1 Outline of Fundamentals.- 3.2 Calculating Gibbs Energies for Overall Reactions.- 3.3 Equilibrium Galvanic Cells.- 3.4 Galvanic Cells with Transference.- 3.5 More on Equilibrium Electrode Potentials.- 3.6 Calculating Elevated-Temperature Gibbs Energies.- References.- 4 The Electrolytic Mechanism of Corrosion.- 4.1 Overview.- 4.2 Reactions, Currents, and Potentials in Galvanic Cells.- 4.3 Measuring Current-Potential Curves.- 4.4 Uniform Corrosion: The Work of Wagner and Traud.- References.- 5 The Kinetics of Electrode Reactions.- 5.1 Hydrogen Deposition and Hydrogen lonisation.- 5.2 Oxygen Reduction and Oxygen Evolution.- 5.3 Metal Dissolution and Metal Deposition.- 5.4 Closer Inspection of the Electrical Double Layer.- References.- 6 Uniform Electrolytic Corrosion.- 6.1 Acid and Neutral Solutions.- 6.2 Neutral and Alkaline Solutions.- 6.3 The Dependence of Corrosion Rates on Temperature.- References.- 7 Adsorption Inhibitors of Acid Iron Corrosion.- References.- 8 Corrosion of Homogeneous Alloys.- 8.1 Introduction.- 8.2 Uniform Dissolution.- 8.3 Selective Dissolution and Dealloying.- 8.4 Dealloying of Hume-Rothery Phases and of Martensites.- References.- 9 Rusting of Iron and Steel.- References.- 10 Passivity.- 10.1 Introduction.- 10.2 Iron in Acid Solutions.- 10.3 Iron in Weakly Acid, Neutral, and Alkaline Solutions.- 10.4 Chromium and Iron-Chromium Steels.- 10.5 Nickel, Molybdenum, and Stainless Steels.- 10.6 Amorphous and Nanocrystalline Alloys.- 10.7 Semiconducting Oxide Films, Spontaneous Passivation, and Passivating Inhibitors.- 10.8 Titanium, Aluminum.- 10.9 Zinc, Magnesium.- 10.10 Oxide Films on Steels in High-Temperature Aqueous Solutions.- References.- 11 Galvanic Corrosion Cells.- 11.1 Dissimilar Metal Contact Corrosion.- 11.1.1 Introduction.- 11.1.2 Cells with Homogeneous Distribution of Current and Potential.- 11.1.3 Contact Corrosion Cells with Coplanar Electrodes.- 11.2 Differential Aeration Cells.- 11.3 Modeling Concentration Fields in Galvanic Cells.- References.- 12 Pitting Corrosion.- 12.1 General Aspects.- 12.2 Breakdown of Passivity and Pit Nucleation.- 12.3 Growth of Pit Nuclei.- 12.4 More on Aluminum and Aluminum Alloys.- 12.4.1 Weakly Alkaline Solutions.- 12.4.2 Neutral and Acid Solutions.- 12.4.3 The Nature of the Pitting Potential.- 12.5 More on Iron, Nickel, and Stainless Steel.- 12.6 A Note on Crevice Corrosion.- References.- 13 Intercrystalline and Intracrystalline Corrosion.- References.- 14 Hydrogen Embrittlement.- 14.1 Introduction.- 14.2 HIC by High-Activity Hydrogen in Low Strength Steels.- 14.3 HISCC by Low-Activity Hydrogen in High-Strength Steels.- References.- 15 Stress Corrosion Cracking.- 15.1 General Aspects.- 15.1.1 Introduction.- 15.1.2 Typical Results of SCC Testing.- 15.1.3 Modeling Stress Corrosion Mechanisms.- 15.2 Iron and Steels.- 15.2.1 Hydrogen-Induced SCC in High-Strength Steels.- 15.2.2 SCC of Mild Steel in Alkaline, Carbonate, and Nitrate Solutions.- 15.2.3 Stainless Steels.- 15.2.4 SCC in High-Temperature, High-Pressure Water.- 15.3 Titanium and Titanium Alloys.- 15.4 Precipitation Hardening Aluminum Alloys.- 15.5 General Aspects Continued.- References.- 16 Corrosion Fatigue.- 16.1 General Aspects.- 16.2 The Fracture Mechanical Approach.- References.- 17 Appendix.- 17.1 Anodic and Cathodic Protection.- References.- 17.2 Mass Transport by Diffusion.- References.- 17.3 Applications of Fracture Mechanics.- References.- 17.4 Electrode Impedance Spectroscopy.- 17.4.1 Introduction.- 17.4.2 The Basic Equivalent Circuit.- 17.4.3 Real Electrode Impedances.- 17.4.4 Laplace and Fourier Transforms.- 17.4.5 Adsorption and Relaxation Impedance.- 17.4.6 Filmed and Coated Electrodes.- 17.4.7 Some Recent Contributions.- References.- 17.5 Electrode Noise Spectroscopy.- References.

Introduction.- Corrosion Reactions and Corrosion Products.- Chemical Thermodynamics of Corrosion.- The Electrolytic Mechanism of Corrosion.- The Kinetics of Electrode Reactions.- Uniform Electrolytic Corrosion.- Adsorption Inhibitors of Acid Iron Corrosion.- Corrosion of Homogeneous Alloys.- Rusting of Iron and Steel.- Passivity.- Galvanic Corrosion Cells.- Pitting Corrosion.- Intercrystalline and Intracrystalline Corrosion.- Hydrogen Embrittlement.- Stress Corrosion Cracking.- Corrosion Fatigue.

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